Erik T. Ouellette, I. Joseph Brackbill, Amy E. Kynman, Stella Christodoulou, Laurent Maron, Robert G. Bergman, and John Arnold*
Inorg. Chem. 2024, https://doi.org/10.1021/acs.inorgchem.3c04248.
Spectroscopic and Computational Evidence of Uranium Dihydrogen Complexes
IJ Brackbill, T Rajeshkumar, L Maron, RG Bergman, J Arnold
Journal of the American Chemical Society, 2024, 146 (2), 1257-1261.
A versatile strategy for the formation of hydride-bridged actinide–iridium multimetallics
Christopher Z. Ye, I Del Rosal, MA Boreen, ET Ouellette, DR Russo, Laurent Maron, John Arnold
Chemical science, 2023, 14 (4), 861-868
"Heterobimetallic-Mediated Dinitrogen Functionalization: N–C Bond Formation at Rhenium-Group 9 Diazenido Complexes"
Erik T. Ouellette, Julian S. Magdalenski, Robert G. Bergman, and John Arnold. Inorg. Chem., 2022, https://doi.org/10.1021/acs.inorgchem.2c02463
"Porphyrinoid actinide complexes"
Gabriela I. Vargas-Zúñiga, Michael A. Boreen, Daniel N. Mangel, John Arnold, and Jonathan L. Sessler. Chem. Soc. Rev. 2022, 51, 3735-3758.
Anukta Jain, Jade I. Fostvedt, Benjamin M. Kriegel, Lauren N. Grant, David W. Small, Robert G. Bergman, and John Arnold. Inorg. Chem. 2022, 61, 6574-6583.
Erik T. Ouellette, Julian S. Magdalenski, Robert G. Bergman, and John Arnold. Acc. Chem. Res. 2022, 55, 783-793.
"A Uranium(II) Arene Complex That Acts as a Uranium(I) Synthon"
Mark D. Straub, Erik T. Ouellette, Michael A. Boreen, R. David Britt, Khetpakorn Chakarawet, Iskander Douair, Colin A. Gould, Laurent Maron, Iker Del Rosal, David Villarreal, Stefan G. Minasian, and John Arnold. J. Am. Chem. Soc. 2021, 143, 19748-19760.
Erik T. Ouellette, Jorge Ivan Amaro Estrada, Daniel J. Lussier, Khetpakorn Chakarawet, Trevor D. Lohrey, Laurent Maron, Robert G. Bergman, and John Arnold. Organometallics 2021, DOI: https://doi.org/10.1021/acs.organomet.1c00516
"A Diverse Array of C-C Bonds Formed at a Tantalum Metal Center"
Jade I. Fostvedt, Michael A. Boreen, Robert G. Bergman, and John Arnold. Inorg. Chem. 2021, 60, 9912–9931.
"Thorium amidates function as single-source molecular precursors for thorium dioxide"
Mark D. Straub, Erik T. Ouellette, Michael A. Boreen, Jacob A. Branson, Alex Ditter, A. L. David Kilcoyne, Trevor D. Lohrey, Matthew A. Marcus, Maria Paley, Jose ́ Ramirez, David K. Shuh, Stefan G. Minasian and John Arnold. Chem. Commun. 2021, 57, 4954 - 4957.
"Amidinate Supporting Ligands Influence Molecularity in Formation of Uranium Nitrides"
Mark D. Straub, Liane M. Moreau, Yusen Qiao, Erik T. Ouellette, Michael A. Boreen, Trevor D. Lohrey, Nicholas S. Settineri, Stephan Hohloch, Corwin H. Booth, Stefan G. Minasian, and John Arnold. Inorg. Chem. 2021, 60, 6672–6679.
"σ or π? Bonding interactions in a series of rhenium metallotetrylenes"
Erik T. Ouellette, Ambre Carpentier, I. Joseph Brackbill, Trevor D. Lohrey, Iskander Douair, Laurent Maron, Robert G. Bergman and John Arnold. Dalton Trans. 2021, 50, 2083 - 2092.
"Perturbation of 1JC,F Coupling in Carbon–Fluorine Bonds on Coordination to Lewis Acids: A Structural, Spectroscopic, and Computational Study"
Brighton A. Skeel, Michael A. Boreen, Trevor D. Lohrey, and John Arnold. Inorg. Chem. 2020, 59, 17259-17267
"1,2-Addition and cycloaddition reactions of niobium bis(imido) and oxo imido complexes"
"Recent Advances in Nuclear Forensic Chemistry"
"Structure and magnetism of a tetrahedral uranium(III) β-diketiminate complex."
Michael Boreen, Colin Alexander Gould, Corwin H. Booth, Stephan Hohloch and John Arnold. Dalton Trans. 2020, 49, 7938-7944
"Facile Activation of Triarylboranes by Rhenium(V) Oxo Imido Complexes."
Trevor D. Lohrey, Emmanuel A. Cortes, Robert G. Bergman, John Arnold. Inorg. Chem. 2020, 59, 7216–7226.
"Lewis acid capping of a uranium(v) nitride via a uranium(iii) azide molecular square."
"Electron acceptors promote proton–hydride tautomerism in low valent rhenium β-diketiminates."
Trevor D. Lohrey, Jade I. Fostvedt, Robert G. Bergman, and John Arnold. Chemical Communications, 2020, 56, 3761 - 3764.
"Synthesis and Structure of Uranium–Silylene Complexes."
"Reactivity of terminal imido complexes of group 4–6 metals: Stoichiometric and catalytic reactions involving cycloaddition with unsaturated organic molecules." Kento Kawakita, Bernard F.Parker, Yuya Kakiuchi, Hayato Tsurugi, Kazushi Mashima, John Arnold, Ian A. Tonks. Coordination Chemistry Reviews, 2020, 407, 213118.
"Controlling dinitrogen functionalization at rhenium through alkali metal ion pairing."
Trevor D. Lohrey, Robert G. Bergman, and John Arnold. Dalton Trans., 2019, 48, 17936 - 17944.
"In-plane Thorium(IV), Uranium(IV), and Neptunium(IV) Expanded Porphyrin Complexes"
James T. Brewster, Daniel N. Mangel, Andrew J. Gaunt, Douglas P. Saunders, Hadiqa Zafar, Vincent M Lynch, Michael A. Boreen, Mary E. Garner, Conrad A. P. Goodwin, Nicholas S. Settineri, John Arnold, Jonathan L. Sessler. J. Am. Chem. Soc. 2019, 141, 17867-17874.
"Structural diversity in multinuclear tantalum polyhydrides formed via reductive hydrogenolysis of metal–carbon bonds"
Jade I. Fostvedt, Trevor D. Lohrey, Robert G. Bergman and John Arnold. Chem. Commun. 2019, 55, 13263 - 13266.
"α-Diimine-Niobium Complex-Catalyzed Deoxychlorination of Benzyl Ethers with Silicon Tetrachloride"
Bernard F. Parker, Hiromu Hosoya, John Arnold, Hayato Tsurugi, Kazushi Mashima, Inorg. Chem. 2019, 58, 12825-12831.
"Hydrodehalogenation of alkyl halides catalyzed by a trichloroniobium complex with a redox active α-diimine ligand
Haruka Nishiyama, Hiromu Hosoya, Bernard F. Parker, John Arnold, Hayato Tsurugi and Kazushi Mashima. Chem. Commun. 2019, 55, 7247-7250.
"Dioxygen reacts with metal-carbon bonds in thorium dialkyls to produce bis(alkoxides)."
Nicholas S Settineri, Angela Shiau and John Arnold, Dalton Trans., 2019, 48, 5569-5573.
"A Uranium Tri-Rhenium Triple Inverse Sandwich Compound"
Michael A. Boreen, Trevor D. Lohrey, Guodong Rao, R. David Britt, Laurent Maron, and John Arnold, J.Am. Chem. Soc., 2019, 141, 5144-5148.
"Siderophore-inspired chelator hijacks uranium from aqueous medium."
Alexander S. Ivanov, Bernard F. Parker, Zhicheng Zhang, Briana Aguila, Qi Sun, Shengqian Ma, Santa Jansone-Popova, John Arnold, Richard T. Mayes, Sheng Dai, Vyacheslav S. Bryantsev, Linfeng Rao & Ilja Popovs. Nature Communications, 2019, 10, 819.
"A Heterotetrametallic Re-Zn-Zn-Re Complex Generated by an Anionic Rhenium(I) β-Diketiminate."
Trevor D. Lohrey, Laurent Maron, Robert G. Bergman, and John Arnold, J.Am. Chem. Soc., 2019, 141, 800-804.
"Isolation of a TMTAA‐Based Radical in Uranium bis‐TMTAA Complexes."
"Synthetic route to white phosphorus (P4) and arsenic triphosphide (AsP3)"
"Two-electron oxidation of a homoleptic U(III) guanidinate complex by diphenyldiazomethane."
Nicholas S. Settineri, Angela A. Shiau, and John Arnold, Chem. Comm, 2018, 54, 10913 - 10916.
Michael A. Boreen and John Arnold. Polyhedron, 2018, 155, 149-152.
"Multiple Bonding in Actinide Chemistry."
"Reductions of a Rhenium(III) Terminal Oxo Complex by Isocyanides and Carbon Monoxide."
Trevor D. Lohrey, Robert G. Bergman and John Arnold. Organometallics 2018, 37, 3552-3557.
"Chemical structure and bonding in a thorium(III)–aluminum heterobimetallic complex."
Alison B. Altman, Alexandra C. Brown, Guodong Rao, Trevor D. Lohrey, R. David Britt, Laurent Maron, Stefan G. Minasian, David K. Shuh and John Arnold. Chemical Science, 2018, 9, 4317 - 4324.
"Interactions of vanadium(IV) with amidoxime ligands: redox reactivity."
B. F. Parker, S. Hohloch, J. R. Pankhurst, Z. Zhang, J. B. Love, J. Arnold and L. Rao, Dalton Trans., 2018, 47, 5695 - 5702.
"Hydroboration Reactivity of Niobium Bis(N-heterocyclic carbene)borate Complexes"
"Insertion, protonolysis and photolysis reactivity of a thorium monoalkyl amidinate complex"
Nicholas S. Settineri and John Arnold, Chemical Science, 2018, 9, 2831 - 2841.
"Homoleptic U(III) and U(IV) Amidate Complexes."
"An overview and recent progress in the chemistry of uranium extraction from seawater."
Bernard F. parker, Zhicheng Zhang, Linfeng Rao, and John Arnold. Dalton Trans., 2018, 47, 639-644.
"Synthesis, characterization, and epoxide ring-opening reactivity of thorium-NHC-bpy complexes."
"f-Block complexes of a m-terphenyl dithiocarboxylate ligand."
"Origin of the unusually strong and selective binding of vanadium by polyamidoximes in seawater."
Trevor Lohrey, Robert Bergman, and John Arnold. Angew. Chemie, Intl. Ed. 2017, 56, 14241-14245.
"Thorium Metallacycle Facilitates Catalytic Alkyne Hydrophosphination."
"Benzoquinonoid-bridged dinuclear actinide complexes."
"Synthesis and Redox Chemistry of a Tantalum Alkylidene Complex Bearing a Metallaimidazole Ring."
Benjamin M. Kriegel, Nikolas Kaltsoyannis, Ruchira Chatterjee, Robert G. Bergman, and John Arnold.
Organometallics, 2017, 36, 3520-3529.
"Reductive Elimination of Diphosphine from a Thorium–NHC–Bis(phosphido) Complex."
Mary E. Garner and John Arnold, Organometallics, 2017, 36, 4511-4514
"A Thorium Chalcogenolate Series Generated by Atom Insertion into Thorium–Carbon Bonds."
Nicholas S. Settineri , Mary E. Garner , and John Arnold, J.Am. Chem. Soc., 2017, 139, 6261–6269.
"Tools for Green Molecular Design to Reduce Toxicological Risk."
David Faulkner, Leah K. Rubin Shen, Vanessa Y. De La Rosad , Dale E. Johnson , Rachel Hemingway , Richard V. Williams, Philip N. Judson , John Arnold and Chris D. Vulpe. Computational Systems Pharmacology and Toxicology, 2017, 31, 36-59.
"Redox-Initiated Reactivity of Dinuclear β-Diketiminatoniobium Imido Complexes."
Benjamin M. Kriegel, Lara C. E. Naested, Grégory Nocton, K. V. Lakshmi⊥, Trevor D. Lohrey, Robert G. Bergman, and John Arnold. Inorg. Chem. 2017, 56, 1626–1637.
"Synthesis and reactivity of tantalum corrole complexes."
Jessica A Ziegler, Heather L Buckley and John Arnold, Dalton Transactions, 2017, 46, 780 - 785.
“A Homoleptic Uranium(III) Tris(aryl) Complex”
"Oxygen Atom Transfer and Intramolecular Nitrene Transfer in a Rhenium β-Diketiminate Complex."
Trevor D. Lohrey, Robert G. Bergman*, and John Arnold*, Inorg. Chem., 2016, 55, 11993–12000.
“Control of Clustering Behavior in Anionic Lanthanide(III) Corrole Complexes: From Oligomers to Monomers”
"Carbon–Nitrogen Bond Cleavage by a Thorium-NHC-bpy Complex."
Mary E. Garner, Stephan Hohloch, Dr. Laurent Maron, John Arnold. Angew. Chemie, Intl. Ed. 2016, 55, 13993-13996.
Mary E. Garner, Stephan Hohloch, Laurent Maron, and John Arnold. Organometallics, 2016, 35, 2915-2922.
“Unusual κ1 Coordination of a β-Diketiminate Ligand in Niobium Complexes.”
Jessica A. Ziegler, Robert G. Bergman, and John Arnold,Dalton Trans. 2016, 45, 12661 - 12668.
On the non-innocence of “Nacnacs”: ligand-based reactivity in β-diketiminate supported coordination compounds.
Clément Camp and John Arnold, Dalton Transactions, 2016, 45, 14462-14498.
β-diketiminate ligands in group 5 metal chemistry.
Activation of Heteroallenes by Coordinatively Unsaturated Nickel(II) Alkyl Complexes Supported by the Hydrotris(3-phenyl-5-methyl)pyrazolyl Borate (TpPh,Me) Ligand.
Mark Abubekerov, Léonard Y. M. Eymann, Thomas L. Gianetti, John Arnold, Dalton Trans. 2016, 45, 14581-14590.
Photo-activation of d0 niobium imido azides: en route to nitrido complexes.
Clément Camp, Lauren N. Grant,Robert G. Bergman, and John Arnold. Chem. Comm., 2016, 52, 5538-5541.
Structural and spectroscopic studies of a rare non-oxido V(V) complex crystallized from aqueous solution.
Nitrene Metathesis and Catalytic Nitrene Transfer Promoted by Niobium Bis(imido) Complexes.
Benjamin M. Kriegel, Robert G. Bergman, and John Arnold. J. Am. Chem. Soc., 2016, 138, 52-55.
N-N Bond Cleavage in a Nitrous Oxide-NHC Adduct Promoted by a PNP Pincer Cobalt(I) Complex.
Clément Camp, Lara C. E. Naested, Kay Severin, and John Arnold. Special issue of Polyhedron in honor of Malcolm Chisholm. 2016, doi:10.1016/j.poly.2015.09.001
Formation of a Niobium-Aluminum Heterobimetallic Complex via Supporting Ligand Exchange.
Alison B. Altman, C. Das Pemmaraju, John Arnold, Stefan G. Minasian, David Prendergast, David K. Shuh, Tolek Tyliszczak. J. Am. Chem. Soc., 2015, 137, 10304–10316.
C-F sp2 bond functionalization mediated by niobium complexes.
Michael Nechayev, Thomas Gianetti, Robert G Bergman and John Arnold, Dalton Trans., Special Fluorine issue, 2015, 44, 19494 - 19500.
Uranium and Thorium Complexes of the Phosphaethynolate Ion.
Preparation and characterization of a tungsten(V) corrole dichloride complex.
Andreas H. Obenhuber, Thomas L. Gianetti, Robert G. Bergman and John Arnold. Chem. Commun., 2015, 51, 1278 - 1281.
Recent developments in out-of-plane metallocorrole chemistry across the periodic table.
Heather L. Buckley and John Arnold, Dalton Trans., 2015, 44, 30-36.
Electron localization in a mixed-valence diniobium benzene complex.
Thomas L Gianetti, Grégory Nocton, Stefan G. Minasian, Nikolas Kaltsoyannis, A.L. David Kilcoyne, Stosh A. Kozimor, David K. Shuh, Tolek Tyliszczak, Robert G. Bergman, and John Arnold. Che. Sci., 2015, 6, 993 - 1003.
Clement Camp, Laurent Maron, Robert G. Bergman, and John Arnold. J. Am. Chem. Soc, 2014, 136, 17652–17661.
Michael Nechayev, Benjamin M. Kriegel, Thomas L. Gianetti, Robert G. Bergman, and John Arnold. Inorg. Chim. Acta, invited contribution, 2014, 22, 114–119.
Heather L. Buckley, Leah K. Rubin, Mikołaj Chromiński, Brendon J. McNicholas, Katherine H. Y. Tsen, and John Arnold. Inorg. Chem., 2014, 53, 7941-7950
Stoichiometric carbon-carbon bond formation mediated by well defined Nb(III) complexes.
Thomas L. Gianetti, Robert G. Bergman, and John Arnold. Polyhedron, invited contribution, 2014, 84, 19–23.
Alexandr Shafir, Maurice P. Power, Glenn D. Whitener, and John Arnold. Inorg. Synth., 2014, 36, 65-72.
Benjamin M. Kriegel, Robert G. Bergman, and John Arnold. Dalton Trans., invited contribution, 2014, 43, 10046-10056.
John Arnold, Thomas L. Gianetti, and Yannai Kashtan. Nature Chem. 2014, 6, 554.
Thomas L. Gianetti, Robert G. Bergman, and John Arnold. Chem. Sci. 2014, 5, 2517-2524.
Ashleigh L. Ward, Wayne W. Lukens, Connie C Lu, and John Arnold. J. Am. Chem. Soc. 2014, 136, 3647–3654.
Andreas H. Obenhuber, Thomas L. Gianetti, Xavier Berrebi, Robert G. Bergman, and John Arnold. J. Am. Chem. Soc. 2014, 136, 2994–2997.
Unusual activation of H2 by reduced cobalt complexes supported by a PNP pincer ligand.
Sergio S. Rozenel, Rosa Padilla, Clément Campa, and John Arnold. Chem. Comm. 2014, 50, 2612-2614.
Synthesis, structure and reactivity of group 4 corrole complexes.
Rosa Padilla, Heather L. Buckley, Ashleigh L. Ward, and John Arnold. Chem. Comm. 2014, 50, 2922-2924.
Chemistry of reduced monomeric and dimeric cobalt complexes supported by a PNP pincer ligand.
Sergio S. Rozenel, Rosa Padilla, and John Arnold. Inorg. Chem. 2013, 52, 11544–11550.
Henry S. La Pierre, Stefan G. Minasian, Mark Abubekerov, Stosh A. Kozimor, David K. Shuh, Tolek Tyliszczak, John Arnold, Robert G. Bergman, and F. Dean Toste. Inorg. Chem. 2013, 52, 11650–11660.
Synthesis and Characterization of Thorium(IV) and Uranium(IV) Corrole Complexes.
Ashleigh L. Ward, Heather B. Buckley, Wayne W. Lukens, and John Arnold. J. Am. Chem. Soc. 2013, 135, 13965–13971.
Peter F. Driscoll, Elise Deunf, Leah Rubin, John Arnold, and John Kerr. J. Electrochem. Soc. 2013, 160, G3152-G3158.
Mark Abubekerov, Thomas L. Gianetti, Atsushi Kunishita, and John Arnold. Dalton Trans. 2013, 42, 10525-10532
Dis-assembly of a Benzylic CF3 Group Mediated by a Niobium(III) Imido Complex.
Thomas L. Gianetti, Robert G. Bergman, and John Arnold. J. Am. Chem. Soc. 2013, 135, 3771-3783.
Group 5 Imides and Bis(imide)s as Selective Hydrogenation Catalysts.
Thomas L. Gianetti, Henry S. LaPierre, John Arnold. Eur. J. Inorg. Chem. 2013, 3771-3783
Lanthanide Corroles: A New Class of Macrocyclic Lanthanide Complexes.
John Arnold, Heather L. Buckley, Mitchell R. Anstey, and Daniel T. Gryko. Chem. Commun. 2013, 49, 3104-3106.
Thomas L. Gianetti, Grégory Nocton, Stefan G. Minasian, Neil C. Tomson, A. L. David Kilcoyne, Stosh A. Kozimor, David K. Shuh, Tolek Tyliszczak , Robert G. Bergman, and John Arnold. J. Am. Chem. Soc. 2013, 135, 3224-3236.
Carbon Monoxide, Isocyanide, and Nitrile Complexes of Cationic, d0 Vanadium Bisimides: π-Back Bonding Derived from the π Symmetry, Bonding Metal Bisimido Ligand Orbitals.
Henry S. La Pierre, John Arnold, Robert G. Bergman, and F. Dean Toste, Inorg. Chem. 2012, 51, 13334-13344.
Synthesis of lithium corrole and its use as a reagent for the preparation of cyclopentadienyl zirconium and titanium corrole complexes.
Heather L. Buckley , Wayne A. Chomitz , Beata Koszarna , Mariusz Tasior , Daniel T. Gryko , Penelope J. Brothers, and John Arnold, Chem. Commun. 2012, 48, 10766-10768.
Bimetallic Ruthenium PNP Pincer Complex As a Platform to Model Proposed Intermediates in Dinitrogen Reduction to Ammonia.
Sergio Rozenel and John Arnold, Inorg. Chem. 2012, 51, 9730-9739.
Nonprecious Metal Catalysts for Fuel Cell Applications: Electrochemical Dioxygen Activation by a Series of First Row Transition Metal Tris(2-pyridylmethyl)amine Complexes.
Ashleigh Ward, Lior Elbaz, John B. Kerr, and John Arnold, Inorg. Chem. 2012, 51, 4694-4706.
Structures, Physicochemical Properties, and Reactivities of Cobalt(II) Complexes Supported by a Homoscorpionate (Tris(pyrazolyl)borate) Ligand.
Atsushi Kunishita, Thomas L. Gianetti, and John Arnold, Organometallics 2012, 31, 372-380.
Redox Catalysis for Dehydrogenation of Liquid Hydrogen Carrier Fuels for Energy Storage and Conversion.
Peter Driscoll, Elise Deunf, Leah Rubin, Oana Luca, Robert Crabtree, Christopher Chidsey, John Arnold and John Kerr, ECS Trans. 2011, 35, 3-17.
Z-Selective, Catalytic Internal Alkyne Semihydrogenation under H2/CO Mixtures by a Niobium(III) Imido Complex.
Thomas L. Gianetti, Neil C. Tomson, John Arnold, and Robert G. Bergman, J. Am. Chem. Soc. 2011, 133, 14904-14907
Carbon Radical Generation by d0 Tantalum Complexes with α-Diimine Ligands through Ligand-Centered Redox Processes.
Hayato Tsurugi, Teruhiko Saito, Hiromasa Tanahashi, John Arnold, Kazushi Mashima, J. Am. Chem. Soc. 2011, 133, 18673-18683
Evaluating f-Element Bonding from Structure and Thermodynamics.
Stefan G. Minasian, Jamin L. Krinsky, John Arnold, Chem. Eur. J. 2011, 17 (44), 12234-12245.
Metal complexes of Co, Ni and Cu with the pincer ligand HN(CH2CH2PiPr2)2: preparation, characterization and electrochemistry.
Sergio S. Rozenel, John B. Kerr and John ArnoldDalton Trans. 2011, 40, 10397-10405.
Synthesis and Reactivity of Cationic Niobium and Tantalum Methyl Complexes Supported by Imido and Diketiminato Ligands.
Neil C. Tomson, John Arnold, and Robert G. Bergman, Dalton Trans, 2011, 40, 7718-7729.
Z-Selective Semihydrogenation of Alkynes Catalyzed by a Cationic Vanadium Bisimido Complex.
Henry S. La Pierre, John Arnold, F. Dean Toste, Angew. Chem. Int. Ed. 2011, 50 (17), pp 3900-3903
Covalent Lanthanide Chemistry Near the Limit of Weak Bonding: Observation of (CpSiMe3)3Ce-ECp* and a Comprehensive Density Functional Theory Analysis of Cp3Ln-ECp (E = Al, Ga).
Jamin L. Krinsky, Stefan G. Minasian, and John Arnold, Inorg. Chem. 2011, 50, pp 345-357
Preparation, Characterization, and Postsynthetic Modification of Metal-Organic Frameworks: Synthetic Experiments for an Undergraduate Laboratory Course in Inorganic Chemistry.
Kenji Sumida and John Arnold, J. Chem. Ed. 2011, 88, pp 92-94
Synthesis, Characterization, and Reactions of Isolable (β-Diketiminato)niobium(III) Imido Complexes.
Neil C. Tomson, John Arnold, Robert G. Bergman, Organometallics 2010, 29, 5010-5025
Halo, Alkyl, Aryl, and Bis(imido) Complexes of Niobium Supported by the β-Diketiminato Ligand.
Neil C. Tomson, John Arnold, Robert G. Bergman, Organometallics 2010, 29, 2926-2942.
Chromium Complexes Supported by the Multidentate Monoanionic N2P2 Ligand: Reduction Chemistry and Reactivity with Ethylene.
Sergio S. Rozenel, Wayne A. Chomitz, and John Arnold, Organometallics 2009, 28, p6243-6253.
A Comparison of 4f vs 5f Metal-Metal Bonds in (CpSiMe3)3M-ECp* (M = Nd, U; E = Al, Ga; Cp* = C5Me5): Synthesis, Thermodynamics, Magnetism, and Electronic Structure.
Stefan G. Minasian, Jamin L. Krinsky, Jeffrey D. Rinehart, Roy Copping, Tolek Tyliszczak, Markus Janousch, David K Shuh, and John Arnold, J. Am. Chem. Soc 2009, 131, 13767-13783
Synthesis and Reactivity of Titanium and Zirconium Complexes Supported by a Multidentate Monoanionic [N2P2] Ligand.
Wayne A. Chomitz, Andrew D. Sutton, Jamin L. Krinsky and John Arnold, Organometallics 2009, 28, 3338-3349
Substitution and Reaction Chemistry of Cobalt Complexes Supported by [N2P2] Ligands.
Wayne A. Chomitz and John Arnold, Inorg. Chem. 2009, 3274-3286
Synthesis and Characterization of Manganese and Iron Complexes Supported by Multidentate [N2P2] Ligands.
Wayne A. Chomitz and John Arnold, Dalton Trans. 2009, 1714-1720
Use of Tetradentate Monoanionic Ligands for Stabilizing Reactive Metal Complexes.
Wayne A. Chomitz and John Arnold, Chem.-Eur. J. 2009, 15, 2020-2030
Aluminum, Zinc, Cadmium, and Gallium Complexes Supported by a Monoanionic [N2P2] Ligand.
Stefan G. Minasian and John Arnold, Dalton Trans. 2009, 106-110
Surface-Enhanced Raman Spectroscopy for Trace Arsenic Detection in Contaminated Water.
Mulvihill, M.; Tao, A.; Benjauthrit, K.; Arnold, J.; and Yang, P., Angew. Chem. 2008, 47, 6456-6460
An Unusally Diverse Array of Products Formed upon Carbonylation of a Dialkylniobium Complex.
Neil C. Tomson, Andrew Yan, John Arnold, and Robert G. Bergman. J. Am. Chem. Soc. 2008, 130(34), 11262-11263
A Heterobimetallic Complex With an Unsupported Uranium(III)-Aluminum(I) Bond: (CpSiMe3)3U-AlCp*.
Stefan G. Minasian, Jamin L. Krinsky, Valerie A. Williams, and John Arnold, J. Am. Chem. Soc. 2008, 130(31), 10086-10087
Synthesis and reactivity of bis-pentamethylcyclopentadienyl diiododialane (Cp*AlI)2: an aluminium(II) precursor to (Cp*Al)4
Stefan G. Minasian and John Arnold, Chem. Comm. 2008, 4043-4045
Reactivity of a Co(I)[N2P2]Complex With Azides: Evidence for a Transient Co(III) imido species.
Wayne A. Chomitz and John Arnold, Chem. Comm. 2008, 3648 - 3650
Gated Proton Transport in Aligned Mesoporous Silica Films.
Fan, R.; Huh, S.; Yan, R.; Arnold, J.; Yang, P., Nature Mater. 2008, 7, 303-307
Oxygen-Centered Hexatantalum Tetradecaimido Cluster Complexes.
Jamin L. Krinsky, Laura L Anderson, John Arnold, and Robert. G. Bergman, Inorg. Chem. 2008, 47, 1053-1066
First-Row Transition Metal-Halide Complexes Supported by a Monoanionic [N2P2] ligand.
Wayne A. Chomitz, Seth F. Mickenberg and John Arnold, Inorg. Chem. 2008, 47, 373-380
Transition metal dinitrogen complexes supported by a versatile monoanionic [N2P2] ligand.
Wayne A. Chomitz and John Arnold, Chem. Comm. 2007, 4797-4799
Synthesis and Reactivity of Metal Complexes Supported by the Tetradentate Monoanionic Ligand Bis(2-picolyl)(2-hydroxy-3,5-di-tert-butylbenzyl)amide (BPPA).
Wayne A. Chomitz, Stefan G. Minasian, Andrew D. Sutton, and John Arnold, Inorg. Chem. 2007, 46, 7199-7209
Platinum Group Thiophenoxyimine Complexes: Syntheses and Crystallographic/Computational Studies.
Krinsky, J.L.; Arnold, J.; Bergman, R.G., Organometallics 2007, 26, 897 - 909
Synthesis and Properties of Oxygen-CenteredTetradecaimido Hexatantalum Clusters.
Krinsky, J.L.; Anderson, L.L.; Arnold, J.; Bergman, R.G., Angew. Chem. 2007, 46, 369-372.
Atom-Transfer Radical Polymerization on Zinc Oxide Nanowires.
Rupert, B.L.; Mulvihill, M.J.; Arnold, J., Chem. Mater., 2006, 18, 5045 - 5051.
Phenoxytriamine Complexes of Yttrium: Synthesis, Structure and use in the Polymerization of Lactide and Caprolactone.
Westmoreland, I.; Arnold, J, Dalton Trans., 2006, 4155-4163
Neutral and Cationic Alkyl Tantalum Imido Complexes: Synthesis and Migratory Insertion Reactions.
Anderson, L.L.; Arnold, J.; Bergman, R.G., Organometallics, 2006, 25, 3394-3406.
Olefination and Group Transfer Reactions of an Electron Deficient Tantalum Methylidene Complex.
Mullins, S.M.; Bergman, R.G.; Arnold, J., Dalton Trans, 2006, 203-212.
Synthesis of Bifunctional Polymer Nanotubes from Silicon Nanowire Templates via Atom Transfer Radical Polymerization.
Rupert, B.R.; Mulvihill, M.J.; He, R.; Hochbaum, A.; Arnold, J.; Yang, P. J. Am. Chem. Soc. 2005, 127, 16040 - 16041.
Proton-Catalyzed Hydroamination and Hydroarylation Reactions of Anilines and Alkenes: A Dramatic Effect of Counteranions on Reaction Efficiency.
Anderson, L.L.; Arnold, J.; Bergman, R.G. J. Am. Chem. Soc. 2005, 127, 14541-14543.
Synthesis and characterization of mono b-diketiminatosamarium amides and hydrocarbyls.
Cui, C.; Shafir, A.; Schmidt, J.A.; Oliver, A.G.; Arnold, J. Dalton Trans, 2005, 1387-1393.
Synthesis and X-ray structures of metallocenium diamines of iron and cobalt.
Inyushin, S., Shafir A., Sheats, J.E., Minihane, M., Whitten C.E., Arnold, J. Polyhedron (MLH Green Special Issue), 2004, 23, 2937-2942.
Catalytic Hydroamination of Alkynes and Norbornene with Neutral and Cationic Tantalum Imido Complexes.
Anderson, L.L.; Arnold, J.; Bergman, R.G. Org Lett., 2004, 6 2519-2522.
Highly Diastereoselective Reduction of Ferrocene Bis-Imines with Methyllithium and the Formation of C2-Symmetric Zr Complexes.
Shafir, A.; Fiedler, D.; Arnold, J. Chem. Commun, 2003, 2598-2599.
Highly Isospecific Polymerization of Methyl Methacrylate with a Bis(pyrrolylaldiminato)samarium Hydrocarbyl Complex.
Cui, C.; Shafir, A.; Reeder, C.L.; Arnold, J. Organometallics 2003, 22, 3357-3359.
Ferrocene-Based Olefin Polymerization Catalysts: Activation, Structure, and Intermediates.
Arnold, J.; Shafir, A. Organometallics 2003, 22, 567-575.
Zirconium Complexes Incorporating Diaryldiamidoferrocene Ligands: Generation of Cationic Derivatives and Polymerization Activity Towards Ethylene and 1-HexeneArnold, J.; Shafir, A.Inorg. Chim. Acta. 2003, 345, 216-220.
Anionic Triazacyclononanes: New Supporting Ligands in Main Group and Transition Metal Organometallic ChemistrySchmidt, J.A.R; Giesbrecht, G.R.; Cui, C.; Arnold, J.Chem. Commun. 2003, 1025-1033.
Divalent Lanthanide Metal Complexes of a Triazacyclononane-Functionalized Tetramethylcyclopentadienyl Ligand: X-Ray Crystal Structures of [C5Me4SiMe2(iPr2tacn)]LnI.
Schmidt, J.A.R; Giesbrecht, G.R.; Cui, C.; Arnold, J. Organometallics, 2002, 21, 3841-3844.
First-Row Transition Metal Complexes of Sterically-Hindered Amidinates.
Schmidt, J.A.R; Arnold, J. Dalton Transactions, 2002, 3454-3461.
Reactions of N,N',N''-Trimethyl-1,4,7-Triazacyclononane with Butyllithium Reagents.
Arnold, J.; Knapp, V.; Shafir, A.; Schmidt, J.A.R. Dalton Transactions, 2002, 3273-3274.
Synthesis and Characterization of a Series of Sterically-Hindered Amidines and their Lithium and Magnesium Complexes.
Schmidt, J.A.R; Arnold, J. Dalton Transactions, 2002, 2890-2899.
Reactions of a Triazacyclononane Supported Tantalum-Lithium Bridging Alkylidene with Organic Substrates.
Schmidt, J.A.R; Arnold, J. Organometallics 2002, 21, 3426-3433.
An Unsolvated Lithium Trihydroaluminate and the Correponding Trialkynylaluminates Supported by an Anionic Triazacyclononane Ligand.
Cui, C.; Schmidt, J.A.R; Arnold, J. Dalton Transactions, 2002, 2992-2994.
Neutral and Cationic Aluminum Complexes Supported by Sterically-Bulky Amidinate Ligands.
Schmidt, J.A.R; Arnold, J. Organometallics, 2002, 21, 2306-2313.
Formation of 1:1 Complexes of Ferrocene-Containing Salen Ligands with Mg, Ti and Zr.
Shafir, A. Fiedler, D, Arnold, J. Dalton Transactions, 2002, 555-560.
(For a PDF of papers published before 2002, click here.)